Triple oxygen isotope analysis of nitrate using isotope exchange cavity ringdown laser spectroscopy
نویسندگان
چکیده
منابع مشابه
Online Differential Thermal Isotope Analysis of Hydration Water in Minerals by Cavity Ringdown Laser Spectroscopy
We have developed a new method for measuring the isotopic composition (δ18O and δD) of different types of bonded water (e.g., molecular water, hydroxyl) contained in hydrated minerals by coupling a thermal gravimeter (TG) and a cavity ringdown laser spectrometer (CRDS). The method involves precisely step-heating a mineral sample, allowing the separation of the different types of waters that are...
متن کاملCavity Ringdown Laser Spectroscopy (CRDS):
Cavity Ringdown Spectroscopy has become a widely used technique in the optical absorption analysis of atoms, molecules, and optical components. The technique allows the determination of total optical losses within a closed cavity comprised of two or more mirrors, and can be made arbitrarily more sensitive by improvments in the cavity mirror reflectivity. Part of the great attraction that Cavity...
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Measurements of ratios of stable isotopes are used in such diverse fields as petroleum prospecting, medical diagnostics, and planetary exploration. The narrow emission linewidth available from tunable diode lasers permits high-resolution infrared absorption measurements of closely spaced isotopic rovibrational lines. Our dual beam spectrometer uses the sweep integration technique in a spectral ...
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Relatively large (P0.2&) O anomalies in the geologic record have been used to recognize atmospheric processes such as photochemical reactions and to trace changes in the partial pressures of O2 and CO2 in Earth’s atmosphere through time. However, recent oxygen isotope measurements of terrestrial rocks, minerals and waters also reveal common, smaller (but statistically significant) deviations fr...
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The sensitive optical detection technique of cavity ringdown spectroscopy is extended to the wavelength range 197-204 nm. A novel design narrowband Fourier-transform-limited laser is used, and the technique is applied to gas-phase extinction measurements in CO2, SF6, and O2. Further demonstration of the system capabilities is given in high-resolution recordings of the Schumann-Runge (0, 0), (1,...
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ژورنال
عنوان ژورنال: Rapid Communications in Mass Spectrometry
سال: 2018
ISSN: 0951-4198
DOI: 10.1002/rcm.8268